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Darvocet is either 50 or 100 mg of propoxyphene napsylate with either 325 or 650 mg of acetaminophen (the "cet" comes from acetaminophen, like in Percocet/Ultracet/etc.)
Hydrocodone is a much stronger, much more effective drug.
A lot of IOP's only carry Darvon/Darvocet and no hydrocodone. Generally hydrocodone is only available from US OP's.